The following headed the Philippines’ Diplomatic Mission to Myanmar:
| Ambassador | Term | |
| From | To | |
| H.E. Eduardo E. Kapunan Jr. | 22 May 2017 | September 2021 |
| H.E. Alex G. Chua* | 22 February 2013 | 30 March 2017 |
| H.E. Hellen B. De La Vega* | 11 September 2009 | 30 October 2012 |
| H.E. Noel C. Cabrera | 11 May 2007 | 9 April 2009 |
| H.E. Phoebe A. Gomez* | 15 May 2000 | 31 December 2006 |
| H.E. Sonia C. Brady* | 24 April 1995 | 22 July 1999 |
| H.E. Rosalinda V. Tirona | 12 July 1990 | 28 August 1993 |
| H.E. Alfredo L. Almendrala* | 3 November 1986 | 25 November 1989 |
| H.E. Constante Ma. Cruz* | 21 December 1978 | 5 April 1986 |
| H.E. Pablo A. Peña* | 8 February 1969 | 20 January 1976 |
| H.E. Benjamin T. Tirona* | 17 April 1962 | 30 March 1968 |
| H.E. Narciso G. Reyes* | 16 August 1958 | 15 March 1962 |
| H.E. Manuel A. Adeva | 29 September 1956 | 15 August 1958 |
